\[\frac{2\sin\left( \frac{3\pi}{2} - a \right) - 3\cos(\pi - a)}{3\sin(\pi + a) - 2\cos\left( \frac{3\pi}{2} + a \right)} =\]
\[= \frac{- 2\cos a + 3\cos a}{- 3\sin a - 2\sin a} =\]
\[= \frac{\cos a}{- 5\sin a} = - \frac{\text{ctg\ a}}{5}\]
\[ctg\ a = 5:\]
\[- \frac{\text{ctg\ a}}{5} = - \frac{5}{5} = - 1.\]