\[\frac{a - 3b}{b} = 4\]
\[\frac{a}{b} - \frac{3b}{b} = 4\]
\[\frac{a}{b} - 3 = 4\]
\[\frac{a}{b} = 4 + 3 = 7\]
\[\frac{4a + 5b}{a} = \frac{4a}{a} + \frac{5b}{a} = 4 + 5 \cdot \frac{b}{a} =\]
\[= 4 + 5 \cdot \frac{1}{7} = 4 + \frac{5}{7} = 4\frac{5}{7}.\]